A team of researchers from Kyushu University has discovered that using a zeolite material called Na-ZSM-5 can improve the conversion of biomass into olefins, which are essential for making a wide range of products like plastics and pharmaceuticals, by using microwaves. This new method could lead to a more energy-efficient and sustainable chemical industry.

To create complex organic compounds like plastics and pharmaceuticals, simple precursor chemicals are needed. One common method of synthesizing these chemicals is through the reforming of naphtha, which is energy-intensive and releases carbon dioxide. However, alternative sources like cooking oil waste and microalgal oils can also be used to make these chemicals using a process called catalytic cracking with the help of zeolite catalysts.

In their study, the researchers found that heating the zeolite catalysts with microwaves could achieve the required temperature without causing unwanted deposits, known as coking. This method of heating is more energy-efficient compared to conventional heating methods.

The researchers discovered that Na-ZSM-5 was the most effective zeolite catalyst when heated with microwaves, leading to higher conversion efficiency of fatty acid esters into olefins with minimal carbon dioxide production. Additionally, the production of olefins was four times higher when using microwave heating compared to conventional heating.

By analyzing the structural changes in the zeolite when exposed to microwaves, the researchers found that localized temperatures of over 1000°C were achieved, leading to selective production of olefins. This new method of microwave heating could significantly improve biomass conversion and contribute to the sustainability goals of the chemical industry.

Overall, the researchers aim to further enhance microwave-driven catalytic processes to improve yield and energy efficiency, ultimately paving the way for a more sustainable chemical manufacturing industry.



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